1 - Patrick Stewart, Vance Joy

James welcomes actor Patrick Stewart and a musical performance by Vance Joy.

2 - Ron Funches, Justin Quiles

James welcomes actor Ron Funches and a musical performance by Justin Quiles.

3 - Dr. Phil, Teddy Swims

James welcomes television host Dr. Phil and a musical performance by Teddy Swims.

4 - Drew Barrymore, Mary Elizabeth Winstead

James welcomes actress Drew Barrymore and actress Mary Elizabeth Winstead.

5 - Cobie Smulders, Regina Hall

James welcomes actress Cobie Smulders and actress Regina Hall.

6 - Cedric the Entertainer, Gillian Anderson

James welcomes actor Cedric the Entertainer and actress Gillian Anderson.

7 - Angela Bassett, NCT 127

James welcomes actress Angela Bassett and a musical performance by NCT 127.

8 - Ken Jeong, Lola Young

James welcomes actor Ken Jeong and a musical performance by Lola Young.

9 - Joseph Gordon-Levitt, Suni Lee

James welcomes actor Joseph Gordon-Levitt and gymnast Suni Lee.

10 - Nicole Kidman, Melissa McCarthy, Bill Gates

James welcomes actress Nicole Kidman, actress Melissa McCarthy, and philanthropist Bill Gates.

11 - Rihanna, Ben Platt

James interviews Ben Platt who performs "For Forever" from Dear Evan Hansen. Plus, James steps in as Rihanna's assistant ahead of her Savage X Fenty fashion show.

12 - Khloe Kardashian, Jade Bird

James welcomes TV personality Khloe Kardashian and a musical performance by Jade Bird.

13 - Mayim Bialik, Gillian Jacobs

James welcomes actress Mayim Bialik and actress Gillian Jacobs.

14 - Tyra Banks, Leslie Odom Jr.

James welcomes TV personality Tyra Banks and actor Leslie Odom Jr.

15 - Andy Serkis, Beth Behrs

James welcomes actor Andy Serkis and actress Beth Behrs.

16 - Jamie Lee Curtis, Ludacris, Lord Huron

James welcomes actress Jamie Lee Curtis, rapper/actor Ludacris, and a musical performance by Lord Huron.

17 - Taraji P. Henson, Gabrielle Union, Jake Wesley Rogers

James welcomes actress Taraji P. Henson, actress Gabrielle Union, and musician Jake Wesley Rogers.

18 - Judy Greer, Annaleigh Ashford, Cat Power

James welcomes actress Judy Greer, actress Annaleigh Ashford, and a musical performance by Cat Power.

19 - Daniel Craig, Rami Malek

James welcomes actor Daniel Craig and actor Rami Malek.

20 - Dave Grohl, Kate Beckinsale, Coldplay, Selena Gomez

James welcomes musician Dave Grohl, actress Kate Beckinsale, and a musical performance by Coldplay feat. Selena Gomez.

21 - Hailee Steinfeld, Lee Pace, Coldplay

James welcomes actress Hailee Steinfeld, actor Lee Pace, and a musical performance by Coldplay.

22 - Jamie Foxx, Coldplay, We Are KING, Jacob Collier

James welcomes actor Jamie Foxx and a musical performance by Coldplay feat. We Are KING and Jacob Collier.

23 - Larry David, Coldplay

James welcomes actor Larry David and a musical performance by Coldplay.

24 - Anya Taylor-Joy, Ben Schwartz, Leon Bridges

James welcomes actress Anya Taylor-Joy, actor Ben Schwartz, and a musical performance by Leon Bridges.

25 - Melanie C, David Boreanaz, Finneas

James welcomes singer Melanie C, actor David Boreanaz and a musical performance by Finneas.

26 - Jeffrey Wright, Edgar Wright, Glass Animals

James welcomes actor Jeffrey Wright, director Edgar Wright, and a musical performance by Glass Animals.

27 - Andie MacDowell, Rudi Dharmalingam, Calum Scott

James welcomes actress Andie MacDowell, actor Rudi Dharmalingam, and a musical performance by Calum Scott.

28 - Dr. Anthony Fauci, Nick Kroll, Patton Oswalt

James welcomes Chief Medical Advisor Dr. Anthony Fauci, actor Nick Kroll, and a comedic performance by Patton Oswalt.

29 - Anna Kendrick, O'Shea Jackson Jr., Atsuko Okatsuka

James welcomes actress Anna Kendrick, actor O'Shea Jackson Jr., and comedian Atsuko Okatsuka.

30 - Eva Longoria, J.B. Smoove, Anitta and Saweetie

31 - Jack McBrayer, Alexandra Shipp, Angels & Airwaves

James welcomes actor Jack McBrayer, actress Alexandra Shipp, and a musical performance by Angels & Airwaves.

32 - Tig Notaro, Dr. Michael Eric Dyson, Muna, Phoebe Bridgers

James welcomes actress Tig Notaro, sociology professor Dr. Michael Eric Dyson, band Muna, and singer Phoebe Bridgers.

33 - Gal Gadot, Henry Lloyd-Hughes, Tori Kelly

James welcomes actress Gal Gadot, actor Henry Lloyd-Hughes, and a musical performance by Tori Kelly.

34 - Dwayne Johnson, Avril Lavigne

James welcomes actor Dwayne Johnson and a musical performance by Avril Lavigne.

35 - Andrew Garfield, Jamie Dornan, Laurie Kilmartin

James welcomes actor Andrew Garfield, actor Jamie Dornan, and comedian Laurie Kilmartin.

36 - John Lithgow, Jack Whitehall, King Calaway

James welcomes actor John Lithgow, actor Jack Whitehall, and a musical performance by King Calaway.

37 - Mindy Kaling, Yvonne Orji, Majid Jordan

James welcomes actress Mindy Kaling, actress Yvonne Orji, and a musical performance by Majid Jordan.

38 - Kirsten Dunst, John Cho, Trey Wakeman

James welcomes actress Kirsten Dunst, actor John Cho, and a comedic performance by Trey Wakeman.

39 - Salma Hayek, Keith Urban

James welcomes actress Salma Hayek, plus a talk and musical performance by Keith Urban.

40 - Adrien Brody, Zazie Beetz, Little Simz

James welcomes actor Adrien Brody, actress Zazie Beetz, and a musical performance by Little Simz.

41 - Nicholas Hoult, Aisling Bea, BTS

James welcomes actor Nicholas Hoult, comic Aisling Bea, and a musical performance by BTS.

42 - Jeff Goldblum, Caitriona Balfe, Sophie Buddle

James welcomes actor Jeff Goldblum, actress Caitriona Balfe, and comic Sophie Buddle.

43 - Kristin Chenoweth; Kal Penn

James welcomes Broadway actor and singer Kristin Chenoweth; comedian and actor Kal Penn.

44 - Octavia Spencer; Max Greenfield; Travis

James welcomes actor Octavia Spencer and Max Greenfield. Musical performance by Travis.

45 - Bill Burr; Glenn Howerton; Meghan Trainor

James welcomes comedian and actor Bill Burr; actor Glenn Howerton. Musical performance by Meghan Trainor.

46 - Zachary Levi, Nicole Byer, Nnena

James welcomes comedian Nicole Byer; actor Zachary Levi. Musical performance by Nnena.

47 - Ansel Elgort; Jane Levy; Blair Socci

James welcomes actor Ansel Elgort, actor Jane Levy, and comedian Blair Socci.

48 - Mariah Carey, BTS

James celebrates his 1000th episode with Mariah Carey and musical guest BTS.

49 - Gavin Newsom; Hannah Waddingham; She & Him

James welcomes California governor Gavin Newsom; actor Hannah Waddingham. Musical performance by She & Him.

50 - Katie Couric, Zach Woods, Dave Gahan & Soulsavers

James welcomes journalist Katie Couric; actor Zach Woods. Musical performance by Dave Gahan and Soulsavers.

51 - Dwyane Wade, Tessa Thompson, Andrew Michaan

James welcomes former professional basketball players Dwayne Wade; actress Tessa Thompson. Comedy performance by Andrew Michaan.

52 - Ariana DeBose, RuPaul, Jimmie Allen

Actress Ariana DeBose; TV personality RuPaul.

53 - Kristin Davis, Chloë Grace Moretz, BTS

James welcomes Kristin Davis and Chloe Grace Moretz. BTS performs.

54 - Aaron Sorkin, Sophia Bush

James welcomes Aaron Sorkin and Sophia Bush

55 - Lily Collins, William Jackson Harper, St. Vincent

James welcomes Lily Collins, William Jackson Harper, St. Vincent. Musical performance by St. Vincent.

56 - Jessica Chastain, Penelope Cruz, Andrew Sleighter

James welcomes Jessica Chastain, Penelope Cruz, Andrew Sleighter.

57 - Adam DeVine, Neve Campbell, Japanese Breakfast

James welcomes Adam DeVine, Neve Campbell, Japanese Breakfast.

58 - Dakota Johnson, Josh Gad, Hippo Campus

James welcomes Dakota Johnson, Josh Gad. Musical performance by Hippo Campus.

59 - Rachel Brosnahan, Ed Helms, Samm Henshaw

James welcomes Rachel Brosnahan, Ed Helms, Samm Henshaw.

60 - David Arquette, Nick Thune, Jackie Kashian

James welcomes David Arquette, Nick Thune. Comedic performance by Jackie Kashian.

61 - Christina Ricci, Jeremy O. Harris, Everybody's Talking about Jamie

James welcomes Christina Ricci, Jeremy O. Harris. Musical performance by Everybody's Talking about Jamie.

62 - Sydney Sweeney, Daveed Diggs, Joy Crookes

James welcomes Sydney Sweeney, Daveed Diggs, Joy Crookes.

63 - Jared Leto, David Cross

James welcomes Jared Leto, David Cross.

64 - Patrick Wilson, Brooklyn Beckham, Gunna

James welcomes Patrick Wilson, Brooklyn Beckham, Gunna.

65 - Johnny Knoxville, Nick Offerman, Tolliver

James welcomes Johnny Knoxville, Nick Offerman, Tolliver.

66 - Dave Franco, Annette Bening, The Linda Lindas

James welcomes Dave Franco, Annette Bening. Musical performance The Linda Lindas.

67 - Lily James, Kenneth Branagh, Nicki Minaj

James welcomes Lily James, Kenneth Branagh, Musical performance by Nicki Minaj.

68 - Jenny Slate, Murray Bartlett, Von Miller, Teddy Swims

James welcomes Jenny Slate, Murray Bartlett, Von Miller, Teddy Swims.

69 - Charlie Day, Anna Chlumsky, Bastille

James welcomes Charlie Day, Anna Chlumsky. Musical performance by Bastille.

70 - Aaron Donald, Adam McKay, Rebecca Hall

James welcomes Aaron Donald, Adam McKay, Rebecca Hall.

71 - Chloe Kim, Ike Barinholtz, Parcels

James welcomes Chloe Kim, Ike Barinholtz. Musical performance by Parcels.

72 - Sam Richardson, Haley Bennett, Sam Morril

James welcomes Sam Richardson, Haley Bennett, Sam Morril.

73 - Whitney Cummings, Shaun White, Natalie Hemby

James welcomes Whitney Cummings, Shaun White, Natalie Hemby.

74 - Hilary Duff, Dave Grohl, Carlie Hanson

James welcomes Hilary Duff, Dave Grohl, Carlie Hanson.

75 - Will Arnett, Nathan Chen, Machine Gun Kelly & Willow Smith

James welcomes Will Arnett, Nathan Chen. Musical performance by Machine Gun Kelly & Willow Smith.

76 - Maggie Gyllenhaal, Cynthia Erivo, Kimberly Clark

James welcomes Maggie Gyllenhaal, Cynthia Erivo, Kimberly Clark.

77 - Pamela Adlon, Taika Waititi, Pinegrove

James welcomes Pamela Adlon, Taika Waititi, Pinegrove.

78 - Patrick Stewart, Collin Farrell, Nick Cave & Warren Ellis

James welcomes Patrick Stewart, Collin Farrell, Nick Cave & Warren Ellis.

79 - Camila Cabello & Nathan Lane

James welcomes Camila Cabello & Nathan Lane.

80 - LaKeith Stanfield, Ryan Tedder, One Republic

James welcomes LaKeith Stanfield, Ryan Tedder. Musical performance by One Republic.

81 - Jennifer Garner, Greg Kinnear, 5 Seconds of Summer

James welcomes Jennifer Garner, Greg Kinnear. Musical performance by 5 Seconds of Summer.

82 - Bob Odenkirk, Edi Patterson, Walk the Moon

Bob Odenkirk, Edi Patterson. Musical performance by Walk the Moon.

83 - Adam Scott, Joachim Trier, Maria Bamford

James welcomes Adam Scott, Joachim Trier, Maria Bamford.

84 - Venus Williams, Zach Braff, Akeem Woods

James welcomes Venus Williams, Zach Braff, Akeem Woods.

85 - James Marsden, Minnie Driver, Gayle

James welcomes James Marsden, Minnie Driver. Musical performance by Gayle.

86 - Rosario Dawson, John Cameron Mitchell, Duran Duran

James welcomes Rosario Dawson, John Cameron Mitchell. Musical performance by Duran Duran.

87 - Lizzo, Gabrielle Union, Pillow Queens

James welcomes Lizzo, Gabrielle Union. Musical performance by Pillow Queens.

88 - Olivia Rodrigo, Renate Reinsve, Cirque du Soleil's Ovo.

James welcomes Olivia Rodrigo, Renate Reinsve. Performance by Cirque du Soleil's Ovo.

89 - Sandra Bullock, Channing Tatum, Chris Laker

James welcomes Sandra Bullock, Channing Tatum, Chris Laker.

90 - Rose McIver, Tony Hawk, Yungblud

James welcomes Rose McIver, Tony Hawk. Musical performance by Yungblud.

91 - Jake Johnson, Jay Hernandez

James welcomes Jake Johnson, Jay Hernandez.

92 - Pablo Schreiber, David Duchovny, Christina Perri

James welcomes Pablo Schreiber, David Duchovny, Christina Perri.

93 - Maria Bakalova, Stephen Merchant, Wet Leg

James welcomes Maria Bakalova, Stephen Merchant. Musical performance by Wet Leg.

94 - Lisa Kudrow, Mira Sorvino, Jimmie Allen

James welcomes Lisa Kudrow, Mira Sorvino. Musical performance by Jimmie Allen.

95 - Jamie Lee Curtis, Chris Pine

James welcomes Jamie Lee Curtis, Chris Pine.

96 - Mark Wahlberg, Judy Greer, Sigrid

James welcomes Mark Wahlberg, Judy Greer. Musical performance by Sigrid.

97 - Pedro Pascal, Daisy Edgar-Jones, Toni Cornell

James welcomes Pedro Pascal, Daisy Edgar-Jones, Toni Cornell.

98 - Elle Fanning, Anthony Ramos, UPSAHL

James welcomes Elle Fanning, Anthony Ramos. Musical performance by UPSAHL.

99 - Pete Holmes, Lucy Boynton, Jay Jurden.

James welcomes Pete Holmes, Lucy Boynton, Jay Jurden.

100 - Nicolas Cage, Aaron Paul, Professor Robert Winston

James welcomes Nicolas Cage, Aaron Paul, Professor Robert Winston.

101 - Henry Winkler, Wyatt Russell, Lara Beitz

James welcomes Henry Winkler, Wyatt Russell, Lara Beitz.

102 - Ray Romano, Brooklyn Decker, Joy Downer

James welcomes Ray Romano, Brooklyn Decker, Joy Downer

103 - Jane Fonda, Lily Tomlin, Pete Yorn

James welcomes Jane Fonda, Lily Tomlin, Pete Yorn.

104 - Molly Shannon, Josh Groban, Big Thief

James welcomes Molly Shannon, Josh Groban. Musical performance by Big Thief.

105 - Dakota Fanning, Jamie Bell, T-Pain

James welcomes Dakota Fanning, Jamie Bell, T-Pain

106 - Monica Barbaro, Tom Cruise, Teddy Swims

James welcomes Monica Barbaro, Tom Cruise,Teddy Swims

107 - Mackenzie Davis, Colin Hanks

James welcomes Mackenzie Davis, Colin Hanks

108 - Elizabeth Olsen, Benedict Cumberbatch, Tom Walker

James welcomes actors Benedict Cumberbatch, Elizabeth Olsen with musical performance by Tom Walker

109 - Anthony Anderson, Michael Bublé

James welcomes actors Anthony Anderson, Michael Bublé

110 - Rebel Wilson, Eugenio Derbez, Joe Zimmerman

James welcomes comedian/actor Rebel Wilson, actor Eugenio Derbez with a comedic performance by Joe Zimmerman

111 - Jessica Biel, David Spade, Bastille

James welcomes actors Jessica Biel, David Spade, with a musical performance by Bastille

112 - Niecy Nash, Paul W. Downs, Smashing Pumpkins

James welcomes Niecy Nash, Paul W. Downs, with a musical performance by Smashing Pumpkins

113 - Ciara, Jenna Dewan, Steven Rogers

James welcomes musical artist Ciara, actor Jenna Dewan, and a performance by Steven Rogers.

114 - Hannah Einbinder, Lennon Parham, the cast of "Hadestown"

James welcomes actors Hannah Einbinder and Lennon Parham. With a performance by the cast of "Hadestown"

115 - Sheryl Crow, Rhea Seehorn

James welcomes musical artist Sheryl Crow and actor Rhea Seehorn

116 - Jean Smart, Joshua Jackson, DNCE

James welcomes actors Jean Smart, Joshua Jackson. With a musical performance by DNCE

117 - Kaley Cuoco, Glen Powell, Bloc Party

118 - Ben Schwartz, Patricia Arquette, Ophira Eisenberg

119 - Amanda Peet, Brett Gelman

120 - Terry Crews, June Diane Raphael, Amos Lee

121 - Juliette Lewis, Viggo Mortensen, Benson Boone

122 - Patrick Schwarzenegger, Tig Notaro, Dustin Nickerson

123 - Annette Bening, Ewan McGregor, The Chainsmokers

124 - Rainn Wilson, Adria Arjona, Mark Owen

125 - Melissa McCarthy, Ben Falcone, Rufus Wainwright

126 - Chrissy Teigen, Rose Byrne, Kat Radley

127 - Bill Clinton

128 - RuPaul, Vanessa Bayer, Bishop Briggs

129 - Lil Dicky, Giancarlo Esposito, Betty Who

130 - Constance Wu, Zoë Chao, Bright Eyes

131 - Chris Pratt, Taylor Kitsch, James Bay

132 - Austin Butler, Jeff Goldblum, Zac Brown Band

133 - Billie Eilish, David Harbour, Lizzo

Broadcasting from London, James welcomes singer-songwriter Billie Eilish and actor David Harbour. James also does Carpool Karaoke with Lizzo.

134 - Vin Diesel, Ed Sheeran, Maisie Peters

135 - John Boyega, Minnie Driver, Lior Suchard, Sam Smith, Cat Burns

136 - Joe Biden, Jamie Dornan, Tessa Thompson

137 - Kevin Hart, Alison Brie

138 - Jason Momoa, Kristen Bell, Meghan Trainor, Teddy Swims

139 - Connie Britton, Aasif Mandvi, Blackbear

140 - Regina Hall, Sterling K. Brown, the cast of “Moulin Rouge! The Musical”

141 - Heidi Klum, David LaChapelle, Ian Karmel

142 - Guy Fieri, Kirby Howell-Baptiste, Sabrina Carpenter

143 - Cristin Milioti, Aisha Tyler, Franz Ferdinand

144 - Terry Crews, Ken Jeong, Amanda Shires